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101.
102.
Polycyclic aromatic hydrocarbons in effluents from wastewater treatment plants and receiving streams in Tianjin, China 总被引:1,自引:0,他引:1
Weixiao Qi Huijuan Liu Jiuhui Qu Chengzhi Hu Huachun Lan Michael Berg Huimin Ren Wei Xu 《Environmental monitoring and assessment》2011,177(1-4):467-480
Surface water, suspended particulate matter, pore water, and sediment samples were collected and analyzed for polycyclic aromatic hydrocarbons (PAHs) in Yongding New River, South Drainage Canal and North Drainage Canal, which receive most of wastewater from industrial city of Tianjin. PAH concentrations in effluent samples of wastewater treatment plants (WTP) discharging into the South Drainage Canal and North Drainage Canal were quantified for the first time. The results showed that the discharge of the WTPs recently only contributed to the PAH contamination in the canals near the outlets of the WTPs. PAH levels in sediments of the streams were greatly higher than those in soils by riverbank probably due to receiving large amounts of untreated wastewater. Unusually high benz[a] anthracene concentration strongly influenced the seasonal and spatial variation of total PAH concentrations in South Drainage Canal. Paired samples t test of ??Nap, Fl, Phe, Fluo and ??Nap, Phe, Fluo, Chry concentrations, which were dominant components in the air samples from non-heating and heating season, respectively, in the suspended particulate matters from the streams showed that PAH source from air deposition was more important for Yongding New River than that for South Drainage Canal and North Drainage Canal. Source apportionment based on PAH profiles indicated that coal combustion was the major PAH contamination source, and coke oven sources and wood combustion also contributed to the PAH contamination of the streams. This was further indicated by organic petrography analysis. 相似文献
103.
Menghong Hu Youji Wang Sau Ting Tsang Siu Gin Cheung Paul K. S. Shin 《Marine Biology》2011,158(7):1591-1600
Energy budget is one of the most studied parameters in aquatic animals under environmental challenge. To examine how prolonged
starvation would affect their energy budget, respiration rate (RR), ammonia excretion rate (ER), oxygen consumption to ammonia–nitrogen
excretion (O:N) ratio and scope for growth (SfG) representing the balance between energy intake and metabolic output, two
Asian horseshoe crab species, Tachypleus tridentatus and Carcinoscorpius rotundicauda, were investigated in two feeding regimes (fed and starved) over a period of 7 weeks. No significant effects of species and
time course, as well as their interaction, on absorption efficiency were observed in the fed treatments. For both species,
RR and ER of the starved treatments significantly decreased, while their O:N ratio significantly increased during the experiment.
However, such values for the fed treatments remained relatively stable over the study period. A rapid reduction in SfG was
only apparent in the first week of the starved treatments for both species; thereafter, their SfG remained relatively constant.
In the fed treatments, SfG of T. tridentatus was significantly lower than that of C. rotundicauda throughout the experiment. In general, C. rotundicauda showed a greater decrease in SfG under starvation than T. tridentatus, suggesting that they may have a more competitive life-history strategy for adjusting to poor nutritional conditions. 相似文献
104.
Anping Zhang Xuemei Xie Jing Ye Chunmian Lin Xiaoyan Hu 《Environmental Chemistry Letters》2011,9(3):369-373
In recent years, the stereoselective toxicity of chiral organophosphorus pesticides has received increasing attention from
environmental toxicology scientists. In an attempt to explore the stereoselective effects of chiral organophosphorus pesticides
on non-target organisms and enzymes, this work investigated the stereoselective toxicity and inhibition of malathion, malaoxon
and isomalathion on Daphnia magna and on acid α-naphthyl acetate esterase extracted from wheat flour, respectively. Toxicity differences were observed between
the two enantiomers of malathion and malaoxon and among the four stereoisomers of isomalathion in the LC50 values on D. magna and the IC50 values on acid α-naphthyl acetate esterase. Enantiomers with (R)-configuration in all the tested compounds showed
higher toxicity to D. magna than their (S)-forms and racemic forms. Racemic malaoxon and isomalathion showed the strongest inhibition on acid α-naphthyl
acetate esterase compared to their respective enantiomers and stereoisomers. 相似文献
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106.
Engineered oxide nanoparticles (NPs) are widely applied in insulators, catalyzers, paints, cosmetic products, textiles and semiconductors. Their attachment on cell membrane may lead to cytotoxicity. The effects of Al2O3, Fe2O3, SiO2, TiO2 and ZnO NPs on membrane integrity and fluidity were studied using giant or small unilamellar vesicles in this study. Al2O3 and SiO2 NPs disrupted the oppositely charged membrane, indicating the important role of electrostatic attraction. However, Fe2O3, TiO2 and ZnO NPs did not cause serious membrane disruption as Al2O3 and SiO2 NPs. Membrane fluidity was evaluated by the generalized polarity (GP) values of Laurdan fluorescent emission. SiO2 NPs induce the membrane gelation of both positively and negatively charged membrane. Al2O3 and ZnO NPs induced the gelation of the oppositely charged membrane, but did not cause obvious membrane gelation to the like charged membrane. The phospholipid molecular structural changes after NP exposure were analyzed by Fourier transform infrared (FT-IR) spectroscopy. FT-IR spectra revealed the hydrogen bond formation between NPs and the carbonyl/phosphate groups of phospholipids. Al2O3 and SiO2 NPs showed strongest evidence of hydrogen bonding on their FT-IR spectra. It was consistent with the microscopic observation and fluorescent data that Al2O3 and SiO2 NPs caused more serious membrane disruption and gelation. This study on membrane damage provides further knowledge on the cytotoxicity of nanomaterials and the safety of NP application. 相似文献
107.
Rainwater contains substantial bacteria and rain is an efficient pathway for the dissemination of bacteria from the atmosphere to land and water surfaces.However,quantitative information on rainwater bacteria is very limited due to the lack of a reliable method.In this study,the epifluorescence microscopy enumeration with the LIVE/DEAD BacLight Bacterial Viability Kit stain was verified to quantify the abundance of viable and non-viable bacterial cells in rainwater,with the 4',6-diamidino-2-phenylindole(DAPI) stain for the reference of total cell counts.Results showed that the total counts of bacterial cells by LIVE/DEAD BacLight staining were consistent with those by DAPI staining,and the average detection efficiency was(109 ± 29)%.The ratio of cell count with glutaraldehyde fixation to that without fixation was(106 ± 5)%on average.The bacterial concentration in negative control was usually an order of magnitude lower than that in rainwater samples.However,in case of small precipitation,the abundance in negative control could be more than that in rainwater samples.These results indicate that the enumeration with LIVE/DEAD BacLight bacterial viability assay coupled with glutaraldehyde fixation and careful negative control investigation is an approach applicable to the measurement of the concentration and viability of bacterial cells in rainwater. 相似文献
108.
A simple approach to enhance the photocatalytic activity of red phosphorus(P) was developed.A mechanical ball milling method was applied to reduce the size of red P and to deposit graphene quantum dots onto red P. The product was characterized by scanning electron microscopy, transmission electron microscopy, contact angle measurements, zeta-potential measurements, X-ray diffraction and UV–vis absorption spectroscopy. The product exhibited high visible-light-driven photocatalytic performance in the photodegradation of rhodamine B. 相似文献
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110.